Synthesis and Characterization of Complex Compounds from Cadmium(II) Chloride and Cobalt(II) Chloride with N,N'-Diethylthiourea

Authors

  • Reza Mega Wahyuni Universitas Negeri Malang
  • Husni Wahyu Wijaya Universitas Negeri Malang
  • Meyga Evi Ferama Sari Universitas Negeri Malang
  • I Wayan Dasna Universitas Negeri Malang
  • Nani Farida Universitas Negeri Malang

DOI:

https://doi.org/10.21776/ub.jpacr.2022.011.01.640

Keywords:

Cadmium(II), Cobalt(II), N, N'-diethylthiourea, ionic complex, detu.

Abstract

The synthesis of ionic complexes of cadmium(II) chloride and cobalt(II) chloride with N,N'-diethylthiourea (detu) ligands has not been previously reported. Therefore, in this research, the synthesis was carried out to study the structure and characterization of the two ionic complex compounds. The cadmium(II)-detu ionic complex was synthesized using the direct reaction method with a ratio between Cd(II) salt and detu ligand of 1:2. Meanwhile, the cobalt(II)-detu ionic complex was synthesized with a ratio between Co(II) salt and detu ligand of 2:4. The cadmium(II)-detu and cobalt(II)-detu ionic complexes have melting points of 105-108 ˚C and 122-125 ˚C, respectively. The electrical conductivity of the cadmium(II)-detu and cobalt(II)-detu complexes showed that the complexes were ionic. The FTIR analysis showed the shifting of the C=S functional group’s band to the smaller wavenumber, which indicates the coordinating detu ligand to the cadmium(II) and cobalt(II) through the S atom. The indirect evidence from 1H-NMR showed that CH3 and CH2 only slightly shifted between the free detu ligand and the Cd-detu and Co-detu complexes.

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Author Biographies

  • Reza Mega Wahyuni, Universitas Negeri Malang
    Department of Chemistry, Universitas Negeri Malang
  • Husni Wahyu Wijaya, Universitas Negeri Malang
    Department of Chemistry, Universitas Negeri Malang
  • Meyga Evi Ferama Sari, Universitas Negeri Malang
    Department of Chemistry, Universitas Negeri Malang
  • I Wayan Dasna, Universitas Negeri Malang
    Department of Chemistry, Universitas Negeri Malang
  • Nani Farida, Universitas Negeri Malang
    Department of Chemistry, Universitas Negeri Malang

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Published

2022-03-30

How to Cite

Synthesis and Characterization of Complex Compounds from Cadmium(II) Chloride and Cobalt(II) Chloride with N,N’-Diethylthiourea. (2022). The Journal of Pure and Applied Chemistry Research, 11(1), 1-8. https://doi.org/10.21776/ub.jpacr.2022.011.01.640