Synthesis of Organo-Quartz from Lumajang Sea Sand Using Sodium Dodecyl Benzene Sulfonate (SDBS) Modificator for Adsorption of Fe3+
Dhimas Yudistira, Danar Purwonugroho, Tutik Setianingsih
J. Pure App. Chem. Res. Vol 10, No 1 (2021), pp.
Submitted: March 09, 2020     Accepted: April 16, 2021     Published: April 14, 2021

Abstract



This study aims to determine the effect of sea sand modification with SDBS for adsorption of Fe3+. Sea sand was treated with 0.1 M HCl solution at 25oC. Organo-quartz was prepared at SDBS concentration of below, equal, and above the CMC value by shaking the mixture for 4 hours at 100 rpm. Characterization by FTIR spectrophotometry showed a change in the spectra pattern. The activation caused increasing of -OH silanol while modifications make them decrease. Characterization with SEM showed that the morphology of the sea sand was not uniform with irregular white chunks. The EDX results showed that the dominant elements were C (13.89% ± 10.86), O (40.48% ± 6.58), Si (16.51% ± 8.13), and Fe (11.68% ± 14.38). Adsorption was carried out using Fe3+ at 50 ppm. The Fe3+ analysis was conducted by AAS. The adsorption value by activated sea sand was 58.22% ± 7.23% whereas without treatment sea sand was 70.46% ± 5.54, and the modified sea sand was 53.24% ± 4.86. The lower adsorption is probably caused by the dissolved iron oxides in sea sand during activation.

Keywords : sea sand, quartz, surfactant, SDBS, adsorption


References


[1] Putra, D.E., Prosiding Pertemuan Ilmiah XXVIII HFI Jateng & DIY, 2014, 3.

[2] Government Regulation, PPRI No. 82 of 2001, 2001, Secretary of State, Jakarta.

[3] Rachman, A., Edwin, F., and Sebleku, P., Metalurgi, 2012, 27(3), 263-272.

[4] Liu, J., Ding, W., Wang, R., Wu, Z., Gong, D., Wang, X., and Jiao, B., Appl. Clay Sci, 2018, 163, 100–107.

[5] Widihati, I.G., Journal of Chemistry, 2008, 2(1), 6, 25-30.

[6] Widiarti, N., and Prasetya, A, Jurnal MIPA, 2017, 40(1), 4, 39-42.

[7] Esposito, S., Materials, 2019, 12(4), 668.

[8] de Gennaro, B., Catalanotti, L., Bowman, R.S., and Mercurio, M., J. Colloid Interface Sci., 2014, 430, 178-183.

[9] Putriani, Sintesis Zeolit dari Abu Sekam Padi (Oryza Sativa L.) dengan Penambahan Surfaktan Sodium Dodecyl Benzene Sulfonate (SDBS) sebagai Adsorben Logam Timbal (Pb), Thesis, Universitas Islam Negeri Alauddin, Makassar, 2018.

[10] Syah, A.F., Sudarti., and Harijanto, A., Seminar Nasional Pendidikan Fisika, 2018, 273- 289.

[11] Usman, A.A., and Mashuri, 2019, AIP Conference Proceedings 2120, 050012, 1-8.

[12] Kristianingrum, S., Siswani, E.D., and Suyanta, S., Jurnal Sains Dasar, 2016, 5(1), 10, 7-16.

[13] Silva, V.A.J., Andrade, P.L., Silva, M.P.C., Valladares, L.D.L.S., and Aguiar, J.A., J. Magn. Magn Mater., 2013, 343, 138–143.

[14] Song, Y., Lee, H., Ko, J., Ryu, J., Kim, M., and Sohn, D., Bull Korean Chem Soc, 2014, 35(7), 2009–2012.

[15] Ahangaran, F., Hassanzadeh, A., and Nouri, S., Int. Nano Lett, 2013, 3(1), 1-5.

[16] Du, G.H., Liu, Z.L., Xia, X., Chu, Q., and Zhang, S.M., JSST, 2006, 39(3), 285–291.

[17] Setianingsih, T., Hasanah, U., and Darjito, D., Indones. J. Chem, 2010, 8(3), 348–352.

[18] Mu’ida, F., Modifikasi Pasir Laut dengan CPB (Setilpiridinium Bromida) dan Aplikasinya sebagai Adsorben Parasetamol, Thesis, Universitas Brawijaya, Malang, 2018.

[19] Roto, R., Advanced Surface Engineering Research., 2018, 127-145.


Refbacks

  • There are currently no refbacks.


Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.