Green Microwave-assisted Synthesis of ZnO-Ag Nanocomposite using Clove Oil (Syzygium aromaticum L.) and Its Bioactivity against Staphylococcus aureus
Elvina Dhiaul Iftitah, Rizki Wahyu Aji Wibowo, Masruroh Masruroh, Khoirun Nisyak
J. Pure App. Chem. Res. Vol 9, No 2 (2020), pp. 82-90
Submitted: November 15, 2019     Accepted: August 31, 2020     Published: August 31, 2020
DOI: http://dx.doi.org/10.21776/ub.jpacr.2020.009.02.513

Abstract


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Microwave-assisted synthesis of zinc oxide-silver (ZnO-Ag) nanocomposite using clove (Syzygium aromaticum L.) oil has been investigated. Variation of solvents and irradiation time of microwave was studied. The product characterization was carried out using XRD, FT-IR, and SEM-EDS. The XRD analysis indicates ZnO-Ag nanocomposite has a polycrystalline structure. The ZnO peak was detected at 2θ = 31.99; 34.58 and 68.05, whereas the Ag peak was detected at 2θ = 38.36 and 44.49. The increasing of irradiation time reduces the crystallite size, and generally has size range between 9 and 12 nm. SEM-EDS confirmed the existence of the ZnO-Ag nanocomposite with percentage of Zn (46.89%), O (29.72%) and Ag (23.39%). Moreover, antibacterial evaluation on Staphylococcus aureus give the inhibition zone in 13.3 mm. This result slightly gives better activity than the reference.


Keywords : Clove (Syzygium aromaticum L.), bioreductor, ZnO-Ag nanocomposite, microwave, bioactivity
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