Geochemical Distribution of Copper and Zinc in the Aquatic Sediment of Nyolo Spring Water at Karangploso Malang East Java

Authors

  • Anis Khoirun Nisa Brawijaya University
  • Barlah Rumhayati Brawijaya University
  • Andi Kurniawan Brawijaya University

DOI:

https://doi.org/10.21776/ub.jpacr.2019.008.01.443

Keywords:

copper, zinc, Nyolo spring, BCR sequential extraction method

Abstract

Aquatic sediment has a role for heavy metals sink. Understanding the geochemical fractions of heavy metals in the aquatic sediment can predict the mobility and reactivity of heavy metals fractions that can induce environmental problems. The aim of this study was to determine the distribution of geochemical fractions of copper and zinc in aquatic sediment of Nyolo spring. Sediments samples were taken from five locations along the spring. Geochemical fractions of copper and zinc were extracted using BCR (Community Bureau of Reference) sequential extraction method. The concentration of these metals in each extract was analyzed using AAS. The result showed that overall the sediment consisted of zinc at a higher concentration than copper. Amongst the geochemical fractions, copper and zinc were found dominantly at an oxidizable fraction. As the first fraction, Zn was more bioavailable than copper for biological uptake. Furthermore, based on the Risk Assessment Code (RAC) value, the aquatic sediment of Nyolo Spring was low risk to the Zn and Cu contaminations at most sites, except for Zn in Site III showed a medium risk. This metals fraction will potentially available for organism uptake with the changing of pH sediment or overlying water

Downloads

Download data is not yet available.

Author Biographies

  • Anis Khoirun Nisa, Brawijaya University
    Chemistry Department
  • Barlah Rumhayati, Brawijaya University
    Chemistry Department
  • Andi Kurniawan, Brawijaya University
    Faculty of Fisheries and Marine Science

References

[1] Riani, E., Cordova, M.R. & Arifin, Z., Marine Poll. Bull., 2018, 133, 664-670.

[2] Morillo, J., Usero, J., Gracia, I., Chemosphere,2004, 55(3), 431–442.

[3] Kayastha, P. S., Scientific World.,2014,12 (12), 48-55.

[4] Fathollahzadeh, H., Kaczala, F., Bhatnagar, A., Hogland, W. Environ. Sci. Pollut. Res.2014, 21(4), 2455–2464.

[5] Kang, X., Song, J., Yuan, H., Duan, L., Li, X., Li, N., Liang, X., Qu, B. Ecotox. Environ. Safe.2017, 143, 296–306.

[6] Nemati, K., Bakar, N. K. A., Abas, M. R., Sobhanzadeh, E. J. Hazard. Mater.2011, 192(1), 402–410.

[7] Ma, X., Zuo, H., Tian, M., Zhang, L., Meng, J., Zhou, X., Min, N., Chang, X., Liu, Y. Chemosphere2016, 144, 264–272.

[8] Liu, A., Duodu, G. O., Goonetilleke, A., Ayoko, G. A. Environ. Pollut. 2017, 229, 639–646.

[9] Quevauviller, P., Trends Anal. Chem., 1998, 17 (5), 289-298.

[10] Standar Nasional Indonesia, Analisis Air dan Limbah: Cara uji mangan dan besi secara spektrofotometri serapan atom, 2009, Badan Standarisasi Nasional, Jakarta.

[11] El-Badry, A. E.-M. A., El-Kammar, A. M. Mar. Pollut. Bull.2018, 127, 811–816.

[12] Gu, Y.-G., Lin, Q., Yu, Z.-L., Wang, X.-N., Ke, C., Ning, J.-J. Mar. Pollut. Bull.2015. 101(2), 852-859.

[13] Zhang, C., Yu, Z., Zeng, G., Jiang, M., Yang, Z., Cui, F., Zhu, M., Shen, L., Hu, L. Environ. Int.2014, 73, 270–281.

[14] Goltermen, A. The Chemistry of Phosphate and Nitrogen Compounds in Sediments,2004, Kluwer Academic Publishers, Dordrecht.

[15] Zhang, Y., Gao, X. Estuar. Coast. Shelf Sci.2015, 164, 86–93.

[16] Filgueiras, A. V., Lavilla, I., Bendicho, C. J. Environ. Monit. 2002, 4(6), 823–857.

[17] Gao, X., Zhou, F., Chen, C.-T. A., Xing, Q. Cont. Shelf Res.2015, 104, 25–36.

[18] Du Laing, G., Rinklebe, J., Vandecasteele, B., Meers, E., Tack, F. M. G. Sci. Total Environ.2009, 407(13), 3972–3985.

[19] Zoumis, T., Schmidt, A., Grigorova, L., Calmano, W. Sci. Total Environ.2001, 266(1), 195–202.

[20] Yao, Q., Wang, X., Jian, H., Chen, H., Yu, Z. Mar. Pollut. Bull.2016, 103(1), 159–167.

[21] Firda, F., Mulyani, O., & Yuniarti, A. Soil Rens: Jurnal Ilmiah Lingkungan Tanah Pertanian,2017, 14(2), 9-12.

[22] Ladigbolu, I. A. IOSR J. Environ. Sci. Toxicol. Food Technol.2014, 8(1), 13–16.

[23] Remor, M. B., Sampaio, S. C., de Rijk, S., Vilas Boas, M. A., Gotardo, J. T., Pinto, E. T., Schardong, F. A. Int. J. Sediment Res.2018, 33(4), 406–414.

Downloads

Published

2019-01-28

How to Cite

Geochemical Distribution of Copper and Zinc in the Aquatic Sediment of Nyolo Spring Water at Karangploso Malang East Java. (2019). The Journal of Pure and Applied Chemistry Research, 8(1), 62-72. https://doi.org/10.21776/ub.jpacr.2019.008.01.443