Oxidation of Cellulose and Nanocellulose Isolated from Paraserianthes falcataria by Potassium Permanganate
Nur Ikhtiarini, Masruri MASRURI, Siti Mariyah Ulfa, Nashi Widodo
J. Pure App. Chem. Res. Vol 12, No 3 (2023), pp. 189-197
Submitted: October 22, 2023     Accepted: December 11, 2023     Published: December 29, 2023
DOI: http://dx.doi.org/10.21776/ub.jpacr.2023.012.03.3331

Abstract


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A high crystallinity proportion of cellulose and nanocellulose in some points contribute to the solubility in polar solvent. This paper reports oxidation reaction study by using potassium permanganate of the cellulose and nanocellulose isolated from the soft wood of Paraserianthes falcataria.  The reaction was conducted under acidic condition at 30 and 70°C for 12 and 24 hours. The product was characterized by FTIR, XRD, SEM, DTA-TGA, and solubility test. Oxidation of cellulose resulted in the opening of hemiacetal of glucopyranose chain, as indicated by carbonyl peak recorded in FTIR spectra. The particle size was determined and amorphous product of cellulose and nanocellulose was isolated. In addition, the DTA/TGA analysis indicate the oxidized cellulose give a more stable structure than the nanocellulose.


Keywords : oxidation; cellulose; nanocellulose; characteristic; potassium-permanganate
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