Mild and Efficient Reagents for Oxidation of Alcohols: [MeOCH2(Ph)3P]+[CrO3X]Ö¿, (X=F, Cl)

Authors

  • Amir Lashgari Department of Chemistry, Faculty of Science, Imam Khomeini International University, Qazvin,, Iran
  • Shahriar Ghamami Department of Chemistry, Faculty of Science, Imam Khomeini International University, Qazvin,, Iran

DOI:

https://doi.org/10.21776/ub.jpacr.2015.004.01.190

Keywords:

Chromium(VI), Methoxymethyltriphenylphosphonium, Fluorotrioxochromate, Methoxymethyltriphenylphosphonium Chlorotrioxochromate, Oxidation, Organic substrate.

Abstract

Two fast, mild, and reasonable oxidizing agents, Methoxymethyltriphenylphosphonium Halochromates (VI), [MeOCH2(Ph)3P]+ [CrO3X]ֿ (MMTriPPXC) are synthesized. The preparations of Methoxymethyltriphenylphosphonium Halochromates are new and efficient reagents for the oxidation of primary and secondary alcohols to their corresponding carbonyl compounds in dichloromethane at ambient temperature. These are obtained with relatively short reaction times.  The oxidants/substrates ratios of 1:1 are employed.

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References

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2015-02-13

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How to Cite

Mild and Efficient Reagents for Oxidation of Alcohols: [MeOCH2(Ph)3P]+[CrO3X]Ö¿, (X=F, Cl). (2015). The Journal of Pure and Applied Chemistry Research, 4(1), 12-16. https://doi.org/10.21776/ub.jpacr.2015.004.01.190